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Enhanced hydrogen production from aqueous methanol solution using TiO

Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 197-202 doi: 10.1007/s11705-014-1417-y

摘要： The photocatalytic hydrogen production from aqueous methanol solution using titanium dioxide (TiO ) was investigated in the addition of metal particles including copper, lead, tin, and zinc. The results show that only the addition of copper particles enhances the hydrogen production. The copper usage and reaction temperature were further optimized for TiO /Cu photocatalyts. Under the optimal conditions, the hydrogen production using TiO /Cu as photocatalysts is approximately 68 times higher than that obtained with only TiO .

关键词： photocatalytic hydrogen generation     methanol     copper particles     TiO2     metal-semiconductor interface    

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Liquid metal printing opening the way for energy conservation in semiconductor manufacturing industry

《能源前沿（英文）》 2022年 第16卷 第4期   页码 542-547 doi: 10.1007/s11708-022-0834-8

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Experimental verification of the interface wave method to detect interlaminar damage of a metal multilayer

Bing LI,Xu GENG,Tong LU,Lei QIANG,Minghang LI

《机械工程前沿（英文）》 2015年 第10卷 第4期   页码 380-391 doi: 10.1007/s11465-015-0365-7

摘要：

The interface wave traveling along the boundary of two materials has been studied for nearly a century. However, experiments, engineering applications, and interface wave applications to the non-destructive inspection of interlaminar composite have developed slowly. In this research, an experiment that applies Stoneley waves (a type of interfacial wave between two solid half-spaces) is implemented to detect the damage in a multilayer structure. The feasibility of this method is also verified. First, the wave velocity and wave structure of Stoneley waves at a perfectly bonded aluminum-steel interface are obtained by solving the Stoneley wave dispersion equation of two elastic half-spaces. Thereafter, an experiment is conducted to measure the Stoneley wave velocity of an aluminum-steel laminated beam and to locate interlaminar cracks by referring to the Stoneley wave velocity and echo wave time. Results indicate that the location error is less than 2%. Therefore, Stoneley waves show great potential as a non-destructive inspection method of a multilayer structure.

关键词： crack localization     interface waves     Stoneley waves     interlaminar damage     multilayer structure    

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High heat flux thermal management through liquid metal driven with electromagnetic induction pump

《能源前沿（英文）》 2022年 第16卷 第3期   页码 460-470 doi: 10.1007/s11708-022-0825-9

摘要： In this paper, a novel liquid metal-based minichannel heat dissipation method was developed for cooling electric devices with high heat flux. A high-performance electromagnetic induction pump driven by rotating permanent magnets is designed to achieve a pressure head of 160 kPa and a flow rate of 3.24 L/min, which could enable the liquid metal to remove the waste heat quickly. The liquid metal-based minichannel thermal management system was established and tested experimentally to investigate the pumping capacity and cooling performance. The results show that the liquid metal cooling system can dissipate heat flux up to 242 W/cm2 with keeping the temperature rise of the heat source below 50°C. It could remarkably enhance the cooling performance by increasing the rotating speed of permanent magnets. Moreover, thermal contact resistance has a critical importance for the heat dissipation capacity. The liquid metal thermal grease is introduced to efficiently reduce the thermal contact resistance (a decrease of about 7.77 × 10−3 °C/W). This paper provides a powerful cooling strategy for thermal management of electric devices with large heat power and high heat flux.

关键词： high heat flux     liquid metal     electromagnetic pump     minichannel heat sink     thermal interface material    

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Recent advances of hydrogen production through particulate semiconductor photocatalytic overall water

《能源前沿（英文）》 2022年 第16卷 第1期   页码 49-63 doi: 10.1007/s11708-022-0817-9

摘要： Solar energy-driven photocatalytic water splitting has been investigated for decades to produce clean and renewable green hydrogen. In this paper, the cutting-edge research within the overall water splitting system is summarized from the one-step photocatalytic overall water splitting (POWS) system to the two-step system and the cocatalysts research in this field. In addition, the photocatalytic reaction engineering study is also reviewed which is crucial for future scale-up. This mini-review provides a picture of survey of recent progress of relevant overall water splitting system, with particular attention paid to material system and mechanistic breakthroughs, and highlights the challenge and opportunity of the current system.

关键词： photocatalysis     overall water splitting     hydrogen    

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Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhanced Raman spectroscopy substrate

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 15-23 doi: 10.1007/s11705-022-2177-8

摘要： Recently, various semiconductor/metal composites have been developed to fabricate surface-enhanced Raman spectroscopy substrates. However, low metal loading on semiconductors is still a challenge. In this study, cystine was introduced to increase the accumulation of gold nanoparticles on zinc oxide, owing to the biomineralization property of cystine. Morphological analysis revealed that the obtained ZnO/Au/cystine composite not only had a higher metal loading but also formed a porous structure, which is beneficial for Raman performance. Compared with ZnO/Au, the ZnO/Au/cystine substrate displayed a 40-fold enhancement in the Raman signal and a lower limit of detection (10–11 mol·L−1) in the detection of rhodamine 6G. Moreover, the substrate has favorable homogeneity and stability. Finally, ZnO/Au/cystine displayed excellent performance toward crystal violet and methylene blue in a test based on river water samples. This study provided a promising method to fabricate sensitive semiconductor/noble metal-based surface-enhanced Raman spectroscopy substrates for Raman detection.

关键词： biomineralization     cystine     semiconductor/metal composite     SERS detection     Raman detection    

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Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties

《化学科学与工程前沿（英文）》 2022年 第16卷 第3期   页码 433-442 doi: 10.1007/s11705-021-2066-6

摘要： Copper(I) selenide-nanocrystalline semiconductor was synthesized via one-step mechanochemical synthesis after 5 min milling in a planetary ball mill. The kinetics of synthesis was followed by X-ray powder diffraction analysis and specific surface area measurements of milled 2Cu/Se mixtures. The X-ray diffraction confirmed the orthorhombic crystal structure of Cu2Se with the crystallite size ~25 nm. The surface chemical structure was studied by X-ray photoelectron spectroscopy, whereby the binding energy of the Cu 2p and Se 3d signals corresponded to Cu+ and Se2– oxidation states. Transmission electron microscopy revealed agglomerated nanocrystals and confirmed their orthorhombic structure, as well. The optical properties were studied utilizing ultraviolet-visible spectroscopy and photoluminescence spectroscopy. The direct bandgap energy 3.7 eV indicated a blue-shift phenomenon due to the quantum size effect. This type of Cu2Se synthesis can be easily adapted to production dimensions using an industrial vibratory mill. The advantages of mechanochemical synthesis represent the potential for inexpensive, environmentally-friendly, and waste-free manufacturing of Cu2Se.

关键词： Cu2Se     berzelianite     nanocrystalline semiconductor     mechanochemical synthesis     planetary ball mill    

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中国先进半导体材料及辅助材料发展战略研究

“先进半导体材料及辅助材料”编写组

《中国工程科学》 2020年 第22卷 第5期   页码 10-19 doi: 10.15302/J-SSCAE-2020.05.002

摘要：

目前，以SiC、GaN为代表的第三代半导体材料快速发展，我国亟需抓住战略机遇期，实现先进半导体材料、辅助材料的自主可控，保障相关工业体系安全。本文在分析全球半导体材料及辅助材料研发与产业发展现状的基础上，寻找差距，结合我国现实情况，提出了构建半导体材料及辅助材料体系化发展、上下游协同发展和可持续发展的发展思路，制定了面向2025年和2035年的发展目标。为推动我国先进半导体材料及辅助材料产业发展，提出了建设集成电路关键材料及装备自主可控工程，SiC和GaN半导体材料、辅助材料、工艺及装备验证平台，先进半导体材料在第五代移动通信技术、能源互联网及新能源汽车领域的应用示范工程，并对如何开展三项工程进行了需求分析，设置了具体的工程目标和工程任务。最后，为推动半导体产业的创新发展，从坚持政策推动，企业和机构主导，整合国内优势资源；把握“超越摩尔”的历史机遇，布局下一代集成电路技术；构建创新链，进行创新生态建设等方面提出了对策建议。

关键词： 先进半导体材料     辅助材料     第三代半导体     2035    

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Novel slack-based robust scheduling rule for a semiconductor manufacturing system with uncertain processing

Juan LIU, Fei QIAO, Yumin MA, Weichang KONG

《工程管理前沿（英文）》 2018年 第5卷 第4期   页码 507-514 doi: 10.15302/J-FEM-2018045

摘要：

The NP-hard scheduling problems of semiconductor manufacturing systems (SMSs) are further complicated by stochastic uncertainties. Reactive scheduling is a common dynamic scheduling approach where the scheduling scheme is refreshed in response to real-time uncertainties. The scheduling scheme is overly sensitive to the emergence of uncertainties because the optimization of performance (such as minimum make-span) and the system robustness cannot be achieved simultaneously by conventional reactive scheduling methods. To improve the robustness of the scheduling scheme, we propose a novel slack-based robust scheduling rule (SR) based on the analysis of robustness measurement for SMS with uncertain processing time. The decision in the SR is made in real time given the robustness. The proposed SR is verified under different scenarios, and the results are compared with the existing heuristic rules. Simulation results show that the proposed SR can effectively improve the robustness of the scheduling scheme with a slight performance loss.

关键词： semiconductor manufacturing system     uncertain processing time     dynamic scheduling     slack-based robust scheduling rule    

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Developments in semiconductor thermoelectric materials

Laifeng LI, Zhen CHEN, Min ZHOU, Rongjin HUANG

《能源前沿（英文）》 2011年 第5卷 第2期   页码 125-136 doi: 10.1007/s11708-011-0150-1

摘要： A surge in interest in developing alternative renewable energy technologies has been observed in recent years. In particular, thermoelectrics has drawn attention because thermoelectric effects enable direct conversion between thermal and electrical energy, and provide power generation and refrigeration alternatives. During the past decade, the performance of thermoelectric materials has been considerably improved; however, many challenges continue to exist. Developing thermoelectric materials with superior performance means tailoring interconnected thermoelectric physical parameters-electrical conductivities, Seebeck coefficients, and thermal conductivities for a crystalline system. The objectives of this paper are to introduce the recent developments in semiconductor thermoelectric materials, and briefly summarize the applications of such materials.

关键词： thermoelectric materials     thermoelectric figure of merit     applications    

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Effect of interface adhesion factor on the bearing capacity of strip footing placed on cohesive soil

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1494-1503 doi: 10.1007/s11709-021-0768-y

摘要： The problem related to bearing capacity of footing either on pure soil or on pure rock mass has been investigated over the years. Currently, no study deals with the bearing capacity of strip footing on a cohesive soil layer overlying rock mass. Therefore, by implementing the lower bound finite element limit analysis in conjunction with the second-order cone programming and the power cone programming, the ultimate bearing capacity of a strip footing located on a cohesive soil overlying rock mass is determined in this study. By considering the different values of interface adhesion factor (αcr) between the cohesive soil and rock mass, the ultimate bearing capacity of strip footing is expressed in terms of influence factor (If) for different values of cohesive soil layer cover ratio (Tcs/B). The failure of cohesive soil is modeled by using Mohr−Coulomb yield criterion, whereas Generalized Hoek−Brown yield criterion is utilized to model the rock mass at failure. The variations ofIf with different magnitudes of αcr are studied by considering the influence of the rock mass strength parameters of beneath rock mass layer. To examine stress distribution at different depths, failure patterns are also plotted.

关键词： bearing capacity     soil-rock interface     Hoek−Brown yield criterion     plasticity     limit analysis    

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Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting toward

《能源前沿（英文）》 doi: 10.1007/s11708-023-0881-9

摘要： Sunlight-powered water splitting presents a promising strategy for converting intermittent and virtually unlimited solar energy into energy-dense and storable green hydrogen. Since the pioneering discovery by Honda and Fujishima, considerable efforts have been made in this research area. Among various materials developed, Ga(X)N/Si (X = In, Ge, Mg, etc.) nanoarchitecture has emerged as a disruptive semiconductor platform to split water toward hydrogen by sunlight. This paper introduces the characteristics, properties, and growth/synthesis/fabrication methods of Ga(X)N/Si nanoarchitecture, primarily focusing on explaining the suitability as an ideal platform for sunlight-powered water splitting toward green hydrogen fuel. In addition, it exclusively summarizes the recent progress and development of Ga(X)N/Si nanoarchitecture for photocatalytic and photoelectrochemical water splitting. Moreover, it describes the challenges and prospects of artificial photosynthesis integrated device and system using Ga(X)N/Si nanoarchitectures for solar water splitting toward hydrogen.

关键词： Ga(X)N/Si nanoarchitecture     artificial photosynthesis     water splitting     solar toward hydrogen    

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Multi-objective optimization of surface texture for the slipperswash plate interface in EHA pumps

《机械工程前沿（英文）》 2022年 第17卷 第4期 doi: 10.1007/s11465-022-0704-4

摘要： Well-designed surface textures can improve the tribological properties and the efficiency of the electro-hydrostatic actuator (EHA) pump under high-speed and high-pressure conditions. This study proposes a multi-objective optimization model to obtain the arbitrarily surface textures design of the slipper/swash plate interface for improving the mechanical and volumetric efficiency of the EHA pump. The model is composed of the lubrication film model, the component dynamic model considering the spinning motion, and the multi-objective optimization model. In this way, the arbitrary-shaped surface texture with the best comprehensive effect in the EHA pump is achieved and its positive effects in the EHA pump prototype are verified. Experimental results show a reduction in wear and an improvement in mechanical and volumetric efficiency by 1.4% and 0.8%, respectively, with the textured swash plate compared with the untextured one.

关键词： electro-hydrostatic actuator     axial piston pump     slipper/swash plate interface     multi-objective optimization     surface texture    

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Thermal analysis of lubricated three-dimensional contact bodies considering interface roughness

《机械工程前沿（英文）》 2022年 第17卷 第2期 doi: 10.1007/s11465-022-0672-8

摘要： Surface roughness and thermal action are of remarkable importance in the lubrication performance of mechanical components, especially in extreme conditions. However, available studies mainly focus on the full-film lubrication conditions without considering temperature rise and real 3D surface roughness due to the complexity of surface topography and temperature characteristics. Moreover, studies on the interfacial thermal behaviors of 3D rough surface lubricated contact in an extended range of working conditions remain limited. In this paper, a deterministic mixed thermal elastohydrodynamic lubrication model considering real 3D surface roughness and thermal effects is proposed. In this model, pressure and temperature are coupled with each other, the computation of elastic deformation is accelerated through the discrete convolution and fast Fourier transform method, the temperature field is calculated with the column sweeping technique, and the semi-system method is introduced to improve convergence and numerical stability under severe conditions. The model is validated by comparing its results with available published numerical and experimental results. The thermal behaviors of the contact interface are studied in a wide range of working conditions. The influences of surface roughness and thermal effect on lubrication performance are revealed. The results show that the proposed model can be used as a powerful analysis tool for lubrication performance and temperature prediction in various heavy-load, high-speed lubricated components over a wide range of lubrication conditions.

关键词： thermal elastohydrodynamic lubrication     surface roughness effect     thermal effect     temperature characteristics     severe conditions    

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我国半导体硅片发展现状与展望

张果虎,肖清华,马飞

《中国工程科学》 2023年 第25卷 第1期   页码 68-78 doi: 10.15302/J-SSCAE-2023.01.002

摘要：

硅片是半导体关键的基础材料，我国半导体硅片对外依存度较高，增强硅片的自主保障能力，对提升我国半导体产业整体水平至关重要。本文重点围绕市场主流的8 in、12 in硅片，分析了全球半导体硅片的技术和产业发展现状，研判了全球半导体硅片产业未来的发展趋势，重点分析了我国半导体硅片的发展现状，指出我国半导体硅片在当前市场需求、宏观政策、配套能力、研发投入等利好因素下迎来难得的发展机遇，同时提出我国半导体硅片产业发展面临挑战，在此基础上，从进一步加强顶层设计和宏观规划、强化政策落实和政策持续性、协调支持产业链协同发展、布局研发集成电路先进制程用半导体硅片等方面提出对策建议，以期为推动我国半导体硅片向更高质量发展提供参考。

关键词： 半导体硅片；8 in；12 in；产业协同；先进制程    

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标题 作者 时间 类型 操作

Enhanced hydrogen production from aqueous methanol solution using TiO

Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO

期刊论文

Liquid metal printing opening the way for energy conservation in semiconductor manufacturing industry

期刊论文

Experimental verification of the interface wave method to detect interlaminar damage of a metal multilayer

Bing LI,Xu GENG,Tong LU,Lei QIANG,Minghang LI

期刊论文

High heat flux thermal management through liquid metal driven with electromagnetic induction pump

期刊论文

Recent advances of hydrogen production through particulate semiconductor photocatalytic overall water

期刊论文

Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhanced Raman spectroscopy substrate

期刊论文

Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties

期刊论文

中国先进半导体材料及辅助材料发展战略研究

“先进半导体材料及辅助材料”编写组

期刊论文

Novel slack-based robust scheduling rule for a semiconductor manufacturing system with uncertain processing

Juan LIU, Fei QIAO, Yumin MA, Weichang KONG

期刊论文

Developments in semiconductor thermoelectric materials

Laifeng LI, Zhen CHEN, Min ZHOU, Rongjin HUANG

期刊论文

Effect of interface adhesion factor on the bearing capacity of strip footing placed on cohesive soil

期刊论文

Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting toward

期刊论文

Multi-objective optimization of surface texture for the slipperswash plate interface in EHA pumps

期刊论文

Thermal analysis of lubricated three-dimensional contact bodies considering interface roughness

期刊论文

我国半导体硅片发展现状与展望

张果虎,肖清华,马飞

期刊论文